Mixed Network Former Effect in Ion-Conducting Alkali Borophosphate Glasses: Structure/Property Correlations in the System [M2O]1/3[(B2O3)x(P2O5)1â•fix]2/3 (M = Li, K, Cs)

Abstract

Glasses in the system [M2O]1/3[(B2O3)x(P2O5)1–x]2/3(M = Li, K, Cs) (0.0 ≤ x ≤ 1.0) were prepared by standard melt-quenching procedures, and their physical properties were characterized by thermal analysis, density measurements, and impedance spectroscopy. Their atomic level structures were comprehensively characterized by Raman spectroscopy, by X-ray… (More)

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