Mix and match backbones for the formation of H-bonded duplexes† †Electronic supplementary information (ESI) available: Detailed experimental procedures with spectroscopic characterization data, 31P NMR titration spectra and binding isotherms. See DOI: 10.1039/c5sc04467g Click here for additional dat

@inproceedings{Iadevaia2016MixAM,
  title={Mix and match backbones for the formation of H-bonded duplexes†
†Electronic supplementary information (ESI) available: Detailed experimental procedures with spectroscopic characterization data, 31P NMR titration spectra and binding isotherms. See DOI: 10.1039/c5sc04467g
Click here for additional dat},
  author={Giulia Iadevaia and Alexander E. Stross and Anja Neumann and Christopher A. Hunter},
  booktitle={Chemical science},
  year={2016}
}
The formation of well-defined supramolecular assemblies involves competition between intermolecular and intramolecular interactions, which is quantified by effective molarity. Formation of a duplex between two oligomers equipped with recognition sites displayed along a non-interacting backbone requires that once one intermolecular interaction has been formed, all subsequent interactions take place in an intramolecular sense. The efficiency of this process is governed by the geometric… CONTINUE READING
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