Mild-temperature Mn2(CO)10-photomediated controlled radical polymerization of vinylidene fluoride and synthesis of well-defined poly(vinylidene fluoride) block copolymers.

@article{Asandei2012MildtemperatureMC,
  title={Mild-temperature Mn2(CO)10-photomediated controlled radical polymerization of vinylidene fluoride and synthesis of well-defined poly(vinylidene fluoride) block copolymers.},
  author={Alexandru D Asandei and Olumide I Adebolu and Christopher P Simpson},
  journal={Journal of the American Chemical Society},
  year={2012},
  volume={134 14},
  pages={6080-3}
}
By contrast to typical high-temperature (100-250 °C) telo-/polymerizations of gaseous fluorinated monomers, carried out in high-pressure metal reactors, the visible light, Mn(2)(CO)(10)-photomediated initiation of vinylidene fluoride (bp = -83 °C) polymerization occurs readily from a variety of alkyl, semifluorinated, and perfluorinated halides at 40 °C, in low-pressure glass tubes and in a variety of solvents, including water and alkyl carbonates. Perfluorinated alkyl iodide initiators also… CONTINUE READING
Recent Discussions
This paper has been referenced on Twitter 1 time over the past 90 days. VIEW TWEETS
3 Citations
4 References
Similar Papers

References

Publications referenced by this paper.
Showing 1-4 of 4 references

Boutevin, B. Well Architectured Fluoropolymers: Synthesis, Properties and Applications

  • B. Ameduri
  • Elsevier: Amsterdam,
  • 2010

Contemporary Topics in Polymer

  • D. Valade, C. Boyer, B. Ameduri, B. Boutevin
  • J. Polym. Sci., Part A: Polym. Chem
  • 2006

In Handbook of Radical Polymerization; Matyjaszewski

  • T. Fukuda, A. Goto, Y. Tsujii
  • New York,
  • 2002

Polymeric Materials Encyclopedia

  • Science, Bailey, J W., Tsuruta
  • Eds.; Plenum Press: New York,
  • 1984

Similar Papers

Loading similar papers…