Microwave spectra of O(2)-HF and O(2)-DF: hyperfine interactions and global fitting with infrared data.

@article{Wu2007MicrowaveSO,
  title={Microwave spectra of O(2)-HF and O(2)-DF: hyperfine interactions and global fitting with infrared data.},
  author={Shenghai Wu and Galen Sedo and Erik M Grumstrup and Kenneth R Leopold},
  journal={The Journal of chemical physics},
  year={2007},
  volume={127 20},
  pages={204315}
}
Spectra of the open shell complexes O(2)-HF and O(2)-DF were recorded using Fourier transform microwave spectroscopy. A complete analysis of the hyperfine structure and a global fit including microwave and infrared frequencies [W. M. Fawzy, C. M. Lovejoy, D. J. Nesbitt, and J. T. Hougen, J. Chem. Phys. 117, 693 (2002)] are reported. The Fermi contact interaction between the electron and nuclear spins, the electron spin-nuclear spin dipolar interaction, the nuclear spin-nuclear spin dipolar… CONTINUE READING

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