Microtropiosides A-F: ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae).

@article{Koyama2010MicrotropiosidesAE,
  title={Microtropiosides A-F: ent-Labdane diterpenoid glucosides from the leaves of Microtropis japonica (Celastraceae).},
  author={Yuka Koyama and K. Matsunami and H. Otsuka and T. Shinzato and Y. Takeda},
  journal={Phytochemistry},
  year={2010},
  volume={71 5-6},
  pages={
          675-81
        }
}
From a 1-BuOH-soluble fraction of a MeOH extract of the leaves of Microtropis japonica, collected in the Okinawa islands, six ent-labdane glucosides, named microtropiosides A-F, were isolated together with one known acyclic sesquiterpene glucoside. Their structures were elucidated by a combination of spectroscopic analyses, and their absolute configurations determined by application of the beta-D-glucopyranosylation-induced shift-trend rule in (13)C NMR spectroscopy and the modified Mosher's… Expand

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