• DOI:10.1039/c4nr06865c
• Corpus ID: 205923648

Microsphere assembly of TiO2 mesoporous nanosheets with highly exposed (101) facets and application in a light-trapping quasi-solid-state dye-sensitized solar cell.

@article{Tao2015MicrosphereAO,
  title={Microsphere assembly of TiO2 mesoporous nanosheets with highly exposed (101) facets and application in a light-trapping quasi-solid-state dye-sensitized solar cell.},
  author={Xiyun Tao and Pengchao Ruan and Xiao-rong Zhang and Hongxia Sun and Xingfu Zhou},
  journal={Nanoscale},
  year={2015},
  volume={7 8},
  pages={
          3539-47
        }
}

• Xiyun Tao, Pengchao Ruan, +2 authors Xingfu Zhou
• Published 12 February 2015
• Chemistry
• Nanoscale

The morphology of nano-titania has a significant effect on the photoelectric properties of dye-sensitized solar cells. In this study, microsphere assembly of a TiO2 mesoporous nanosheet constructed by nanocuboids was conducted via a simple hydrothermal process. The XRD pattern indicated that the hierarchical mesoporous microspheres are anatase phase with decreased (004) peaks. Raman spectrum shows enhanced Eg peaks at 143 and 638 cm(-1) caused by the symmetric stretching vibration of O-Ti-O of the (101) crystalline facet in anatase TiO2. FESEM and TEM images show that well monodispersed TiO2 microspheres with a diameter of 2 μm are assembled by TiO2 mesoporous nanosheets with exposed (101) facets. The oriented attachment of TiO2 nanocuboids along the (101) direction leads to the formation of mesoporous titania nanosheets. The UV-Vis spectrum shows that the mesoporous TiO2 nanosheets have high scattering ability and light absorption by dye. Quasi-solid-state dye-sensitized solar cells that incorporate these microspheres into the top scattering layers exhibit a prominent improvement in the power conversion efficiency of 7.51%, which shows a 45.8% increase in the overall conversion efficiency when compared with the spine hierarchical TiO2 microspheres (5.15%). There is the potential application for microsphere assembly of mesoporous TiO2 nanosheets in quasi-solid-state dye-sensitized solar cells with excellent stability.