Microbial oxidation in synthesis: A six step perparation of (+)-pinitol from benzene

@article{Ley1987MicrobialOI,
  title={Microbial oxidation in synthesis: A six step perparation of (+)-pinitol from benzene},
  author={Steven V. Ley and Francine Sternfeld and Stephen John Clifford Taylor},
  journal={Tetrahedron Letters},
  year={1987},
  volume={28},
  pages={225-226}
}
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References

SHOWING 1-5 OF 5 REFERENCES
Zur Chemie des Benzolglykols, IV. Darstellung von cis‐Benzolglykol, stereoisomeren Mucondialdehyden und Kondurit‐F
Durch Oxydation des 3.4.5.6-Tetrachlor-cyclohexens (I) mit Kaliumpermanganat wurde cis-1.2-Dihydroxy-3.4.5.6-tetrachlor-cyclohexan (II) hergestellt. Die Entchlorierung von II mit Zinkstaub ergab das
Plant Constituents biologically Active to Insects. I. Feeding Stimulants for the Larvae of the Yellow Butterfly, Eurema hecabe mandarina. (1)
Biting responses were obtained in the larvae of the yellow butterfly, Eurema hecabe mandarina DE L'ORZA, to four chemical constituents of their host plant, Lespedeza cuneata G. DON, namely,
Inositol trisphosphate, a novel second messenger in cellular signal transduction
TLDR
Diacylglycerol operates within the plane of the membrane to activate protein kinase C, whereas inositol trisphosphate is released into the cytoplasm to function as a second messenger for mobilizing intracellular calcium.