Methoxysulfinyl Radical CH3OSO: Gas-Phase Generation, Photochemistry, and Oxidation.

@article{Liu2017MethoxysulfinylRC,
  title={Methoxysulfinyl Radical CH3OSO: Gas-Phase Generation, Photochemistry, and Oxidation.},
  author={Qifan Liu and Zhuang Wu and Jian Xu and Yan Lu and Hongmin Li and Xiaoqing Zeng},
  journal={The journal of physical chemistry. A},
  year={2017},
  volume={121 19},
  pages={3818-3825}
}
Methylsulfoxide radicals CH3SOx (x = 1-4) are key reactive sulfur species (RSS) in the atmospheric oxidation of volatile organic sulfur compounds (VOSCs). Through flash vacuum pyrolysis (FVP) of trifluoromethanesulfinic acid methyl ester CF3S(O)OCH3 at 1000 K, the methoxysulfinyl radical CH3OSO has been generated in the gas phase and subsequently… CONTINUE READING