Methanimine as a Key Precursor of Imines in the Interstellar Medium: The Case of Propargylimine

@article{Lupi2020MethanimineAA,
  title={Methanimine as a Key Precursor of Imines in the Interstellar Medium: The Case of Propargylimine},
  author={Jacopo Lupi and Cristina Puzzarini and Vincenzo Barone},
  journal={arXiv: Astrophysics of Galaxies},
  year={2020}
}
A gas-phase formation route is proposed for the recently detected propargylimine molecule. In analogy to other imines, such as cyanomethanimine, the addition of a reactive radical (C$_2$H in the present case) to methanimine (CH$_2$NH}) leads to reaction channels open also in the harsh conditions of the interstellar medium. Three possible isomers can be formed in the C$H_2$NH + C$_2$H reaction: Z- and E-propargylimine (Z-,E-PGIM) as well as N-ethynyl-methanimine (N-EMIM). For both PGIM species… Expand

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