Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity.

@article{Madrid2014MetastableID,
  title={Metastable ionic diodes derived from an amine-based polymer of intrinsic microporosity.},
  author={Elena Madrid and Yuanyang Rong and Mariolino Carta and Neil B. McKeown and Richard Malpass-Evans and Gary A. Attard and Tomos J. Clarke and Stuart H Taylor and Yitao Long and Frank Marken},
  journal={Angewandte Chemie},
  year={2014},
  volume={53 40},
  pages={10751-4}
}
A highly rigid amine-based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger's base, is demonstrated to act as an ionic diode with electrolyte-dependent bistable switchable states.