Metal Substitution Effect on a Three-Dimensional Cyanido-Bridged Fe Spin-Crossover Network

@inproceedings{Imoto2017MetalSE,
  title={Metal Substitution Effect on a Three-Dimensional Cyanido-Bridged Fe Spin-Crossover Network},
  author={Kenta Imoto and Shinjiro Takano and Shin-Ichi Ohkoshi},
  year={2017}
}
We report the CoII-substitution effect on a cyanido-bridged three-dimensional FeII spin-crossover network, Fe2[Nb(CN)8](4-pyridinealdoxime)8·2H2O. A series of iron–cobalt octacyanidoniobate, (FexCo1−x)2[Nb(CN)8](4-pyridinealdoxime)8·zH2O, was prepared. In this series, the behavior of FeII spin-crossover changes with the CoII concentration. As the CoII concentration increases, the transition of the spin-crossover becomes gradual and the transition temperature of the spin-crossover shifts towards… CONTINUE READING