Metal Stable Isotopes in Paleoceanography

@article{Anbar2007MetalSI,
  title={Metal Stable Isotopes in Paleoceanography},
  author={Ariel D. Anbar and Olivier J. Rouxel},
  journal={Annual Review of Earth and Planetary Sciences},
  year={2007},
  volume={35},
  pages={717-746}
}
  • A. Anbar, O. Rouxel
  • Published 2007
  • Environmental Science
  • Annual Review of Earth and Planetary Sciences
Considered esoteric only a few years ago, research into the stable isotope geochemistry of transition metals is moving into the geoscience mainstream. Although initial attention focused on the potential use of some of these nontraditional isotope systems as biosignatures, they are now emerging as powerful paleoceanographic proxies. In particular, the Fe and Mo isotope systems are providing information about changes in oxygenation and metal cycling in ancient oceans. Zn, Cu, Tl, and a number of… Expand
View via Publisher
soest.hawaii.edu
263 Citations
Highly Influential Citations
13
Background Citations
81
Methods Citations
10
Results Citations
1

Figures from this paper

263 Citations

Citation Type

Citation Type

Stable Isotope Geobiology
Stable isotopes are tools that geobiologists use to investigate natural and experimental systems, with questions ranging from those aimed at modern environments and extant microorganisms, to deep… Expand
Potential of non-traditional isotope studies for bioarchaeology
As a consequence of recent developments in mass spectrometry, the application of non-traditional stable isotope systems (e.g. Ca, Cu, Fe, Mg, Sr, Zn) as well as radiogenic isotopes to archaeological… Expand
Iron isotopes in an Archean ocean analogue
Abstract Iron isotopes have been extensively used to trace the history of microbial metabolisms and the redox evolution of the oceans. Archean sedimentary rocks display greater variability in iron… Expand
Mo isotopes in the Lower Cambrian formation of southern China and its implications on paleo-ocean environment
Over the past decade, as one of nontraditional stable isotopes, Mo isotope has developed rapidly and now become an important geochemical proxy to trace paleo-oceanic and atmospheric evolution through… Expand
13.3 – Stable Isotope Geochemistry of Mineral Deposits
In this chapter, the intent is to summarize the results of traditional stable isotope studies (mainly H, B, O, C, and S) that have greatly contributed to the understanding of ore-forming processes… Expand
Selenium isotopes trace anoxic and ferruginous seawater conditions in the Early Cambrian
Abstract Selenium (Se) isotopes can yield substantial isotopic fractionation (up to 20‰) confirmed by experiments and field investigations, depending on various biotic or abiotic redox… Expand
Molybdenum isotope variations in magmatic rocks
The application of Mo isotopes to study geodynamic processes is a rather new development that has gained considerable momentum over the past few years. Its redox-sensitivity causes significant… Expand
Iron isotope transformations in the meromictic Lake Cadagno
Abstract The iron isotope composition of sedimentary deposits is a key tool for tracking changes in the biogeochemical and redox conditions of modern and geologically ancient aquatic systems. The use… Expand
Molybdenum isotope fractionation and speciation in a euxinic lake—Testing ways to discern isotope fractionation processes in a sulfidic setting
Abstract The molybdenum (Mo) isotope composition in euxinic shales has been used as a proxy for the global distribution of anoxic conditions in ancient oceans, and since more recently also as a proxy… Expand
Thallium-isotopic compositions of euxinic sediments as a proxy for global manganese-oxide burial
Abstract Thallium (Tl) isotopes are a new and potentially powerful paleoredox proxy that may track bottom water oxygen conditions based on the global burial flux of manganese oxides. Thallium has a… Expand
...
1
2
3
4
5
...

References

SHOWING 1-10 OF 208 REFERENCES
Iron stable isotopes: beyond biosignatures
Abstract The stable isotope geochemistry of Fe has attracted intense interest in the past five years. This interest was originally motivated by the possible use of Fe isotopes in biosignature… Expand
Iron Isotope Constraints on the Archean and Paleoproterozoic Ocean Redox State
TLDR
Variable and negative iron isotope values in pyrites older than about 2.3 Ga suggest that an iron-rich global ocean was strongly affected by the deposition of iron oxides in a redox stratified ocean. Expand
Molybdenum Stable Isotopes: Observations, Interpretations and Directions
The unusual chemistry of molybdenum (Mo) makes this trace element interesting to both geochemists and biochemists. Geochemically, Mo is relatively unreactive in oxygenated, aqueous solutions, and… Expand
Authigenic molybdenum isotope signatures in marine sediments
We present new Mo isotope data from the Mexican continen- tal margin that, in conjunction with previous data, allow us to propose a mechanistic description of the Mo isotope system in ma- rine… Expand
Molybdenum isotope signatures in continental margin marine sediments
Abstract We present molybdenum isotope data for four sediment profiles from continental margin settings. Each profile has a distinctive average isotope composition ranging from δ 98 / 95 Mo − 0.5‰ to… Expand
Ancient geochemical cycling in the Earth as inferred from Fe isotope studies of banded iron formations from the Transvaal Craton
Abstract.Variations in the isotopic composition of Fe in Late Archean to Early Proterozoic Banded Iron Formations (BIFs) from the Transvaal Supergroup, South Africa, span nearly the entire range yet… Expand
Iron isotope constraints on Fe cycling and mass balance in oxygenated Earth oceans
The Fe isotope composition of Proterozoic to modern clastic sedimentary rocks and aerosols defines a range ind 56 Fe values that is only slightly more variable than the range of Fe isotope com-… Expand
The Archean sulfur cycle and the early history of atmospheric oxygen.
TLDR
Sedimentary sulfur isotope record suggests low concentrations of seawater sulfate and atmospheric oxygen in the early Archean and early Proterozoic and shows how sulfate reduction rate influences the preservation of biological fractionations in sediments. Expand
Molybdenum isotope records as a potential new proxy for paleoceanography
New high-precision isotope ratios of dissolved Mo in seawater from different ocean basins and depths show a homogeneous isotope composition (‘mean ocean water 98 Mo/ 95 Mo’ (MOMO)), as expected from… Expand
Germanium isotopic variations in igneous rocks and marine sediments
A new technique for the precise and accurate determination of Ge stable isotope compositions has been developed and applied to silicate rocks and biogenic opal. The analyses were performed using a… Expand
...
1
2
3
4
5
...