Metal-Organic Frameworks with Tb4 Clusters as Nodes: Luminescent Detection of Chromium(VI) and Chemical Fixation of CO2.


Two multifunctional metal-organic frameworks based on cubane-like tetrahedron Tb4 clusters as nodes have been synthesized and characterized. Compound 1 exhibits a 2D lanthanide-organic framework with Tb4 clusters as nodes, and compound 2 possesses a 3D framework with Tb4 clusters and Mn2+ as nodes. Interestingly, luminescent investigations on them reveal… (More)
DOI: 10.1021/acs.inorgchem.7b00323


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