Metal-Cation-Independent Dynamics of Phenylene Ring in Microporous MOFs: A 2H Solid-State NMR Study

@inproceedings{Khudozhitkov2015MetalCationIndependentDO,
  title={Metal-Cation-Independent Dynamics of Phenylene Ring in Microporous MOFs: A 2H Solid-State NMR Study},
  author={Alexander E. Khudozhitkov and Daniil I Kolokolov and Alexander G Stepanov and Vsevolod A. Bolotov and Danil N Dybtsev},
  year={2015}
}
Mobility of the organic linkers in metal–organic frameworks (MOFs) is an established phenomenon. Knowledge of the details of linker motion in MOFs could provide a great deal of information about the linker structure and the way the guest molecules interact with the organic framework. However, the mobility of the organic linkers is poorly characterized. The extent of the influence of the metal cation or guest molecules on linker motion is still unknown for MOFs with identical topologies. In this… CONTINUE READING