Metal–organic framework structures of Cu(II) with pyridine-2,6-dicarboxylate and different spacers: identification of a metal bound acyclic water tetramer

@inproceedings{Ghosh2004MetalorganicFS,
  title={Metal–organic framework structures of Cu(II) with pyridine-2,6-dicarboxylate and different spacers: identification of a metal bound acyclic water tetramer},
  author={Sujit K Ghosh and J. Carvalhal Ribas and Parimal K Bharadwaj},
  year={2004}
}
The ligand pyridine-2,6-dicarboxylic acid (pdcH2) reacts under hydrothermal conditions, with Cu(NO3)2?6H2O in the presence of different N-heterocycles used as spacers to form 1D, 2D or 3D metal–organic framework structures depending on the nature of the spacer. These network structures are characterized by X-ray crystallography, variable temperature magnetic measurements, powder X-ray diffraction, infrared and thermal gravimetric analyses. With 4,4’-bipyridine spacer, a 2D network is formed… CONTINUE READING

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