Melting of orbital ordering in KMgxCu1-xF3 solid solution.


The long-range and short-range structures of KMgxCu1-xF3 (0 < x < 1) have been investigated by means of XRPD and EPR. Two different solid solutions are present, based on the structure of KMgF3 (for x > 0.42) and of KCuF3 (for x < 0.26), respectively, and they are separated by a biphasic zone. Positional disorder is induced by doping due to the different Cu… (More)


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