Mechanistic variations in the oxidation of Piloty's acid by metal complexes.


The reactions of N-hydroxybenzenesulfonamide (Piloty's acid, PA) with a variety of metal oxidants are reported. Either nitric oxide or nitrite is the final reaction product, along with benzenesulfinate and the reduced metal compound. The nitrogen product depends on the oxidation potential of the metal oxidant and its ability to further oxidize NO to nitrite… (More)


Figures and Tables

Sorry, we couldn't extract any figures or tables for this paper.