Mechanistic studies of plasma polymerization of allylamine.


Plasma polymerization of allylamine is performed both in continuous wave and pulsed mode. Chemical derivatization is applied to determine primary and secondary amine concentration. Primary amines are efficiently formed, but secondary amines are more abundant. A polymerization mechanism is proposed to account for the difference in amine content obtained from… (More)


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@article{Choukourov2005MechanisticSO, title={Mechanistic studies of plasma polymerization of allylamine.}, author={Andrei Choukourov and Hynek Biederman and Danka Slav{\'i}nsk{\'a} and Luke Hanley and A. I. Grinevich and Hanna Boldyryeva and Anna Mackov{\'a}}, journal={The journal of physical chemistry. B}, year={2005}, volume={109 48}, pages={23086-95} }