Mechanisms of acid-base catalysis of beta-elimination reactions in systems activated by a pyridine ring.

Abstract

Beta-elimination reactions from 1 (in quinuclidine/quinuclidinium chloride, imidazole/imidazolium, and acetate/acetic acid buffers) and from 2 (in imidazole/imidazolium and acetate/acetic acid buffers) with formation of 4-vinylpyridine and 2-vinylpyridine, respectively, were studied. The results of a kinetic study of acid-base catalysis and H/D exchange are… (More)

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