Mechanism of the oxidation of alcohols by oxoammonium cations.

Abstract

The mechanism of the oxidation of primary and secondary alcohols by the oxoammonium cation derived from 2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) has been investigated computationally at the B3LYP/6-31+G* level, along with free energies of solvation, using a reaction field model. In basic solution, the reaction involves formation of a complex between the… (More)

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Cite this paper

@article{Bailey2007MechanismOT, title={Mechanism of the oxidation of alcohols by oxoammonium cations.}, author={William F Bailey and James M Bobbitt and Kenneth B. Wiberg}, journal={The Journal of organic chemistry}, year={2007}, volume={72 12}, pages={4504-9} }