Mechanism of Photoredox Reactions of Iron(III) Complexes Containing Salen-type Ligands*

  • Jozef ima
  • Published 2003


A mechanism of photoredox processes occurring in irradiated methanolic solutions of transFe(R-salen)(CH3OH)F , where (R-salen)2– are tetradentate open-chain Schiff base N,N'-ethylenebis(5-R-salicylideneiminato) N2O2-ligands (R = F, I, CH3, CF3, OCH3, NO2), has been investigated and proposed. The complexes are redox stable in the dark. The photoreduction of… (More)


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