Measuring Spin-Allowed and Spin-Forbidden d-d Excitations in Vanadium Complexes with 2p3d Resonant Inelastic X-ray Scattering.

Abstract

Spectroscopic probes of the electronic structure of transition metal-containing materials are invaluable to the design of new molecular catalysts and magnetic systems. Herein, we show that 2p3d resonant inelastic X-ray scattering (RIXS) can be used to observe both spin-allowed and (in the VIII case) spin-forbidden d-d excitation energies in molecular… (More)

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