Mathematical Modeling of Commercial LiFePO4 Electrodes Based on Variable Solid-State Diffusivity

@inproceedings{Farkhondeh2011MathematicalMO,
  title={Mathematical Modeling of Commercial LiFePO4 Electrodes Based on Variable Solid-State Diffusivity},
  author={M. Makhdoum Farkhondeh and Charles Delacourt},
  year={2011}
}
AmathematicalmodeloftheLiFePO4 electrodeisdevelopedthatisbasedonathermodynamically-consistenttreatmentofsolid-state lithium transport, in which the active material is described as a nonideal binary solution of Li-intercalated and empty sites. The nonideality is derived from the experimental open-circuit potential and manifested in a concentration-dependent diffusion coefficient throughout the entire composition range. Under certain operating conditions, a diffuse phase-boundary between Li-poor… CONTINUE READING

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