Marked stabilization of redox states and enhanced catalytic activity in galactose oxidase models based on transition metal S-methylisothiosemicarbazonates with -SR group in ortho position to the phenolic oxygen.

@article{Arion2013MarkedSO,
  title={Marked stabilization of redox states and enhanced catalytic activity in galactose oxidase models based on transition metal S-methylisothiosemicarbazonates with -SR group in ortho position to the phenolic oxygen.},
  author={Vladimir B Arion and Sonja Platzer and Peter Rapta and Peter Machata and Martin Breza and Daniel V{\'e}gh and Lothar Dunsch and Joshua Telser and Sergiu S Shova and Tatiana C O Mac Leod and Armando J L Pombeiro},
  journal={Inorganic chemistry},
  year={2013},
  volume={52 13},
  pages={7524-40}
}
Reactions of 5-tert-butyl-2-hydroxy-3-methylsulfanylbenzaldehyde S-methylisothiosemicarbazone and 5-tert-butyl-2-hydroxy-3-phenylsulfanylbenzaldehyde S-methylisothiosemicarbazone with pentane-2,4-dione (Hacac) and triethyl orthoformate in the presence of M(acac)2 as template source at 107 °C afforded metal complexes of the type M(II)L(1) and M(II)L(2… CONTINUE READING