Magnetism in polyoxometalates: anisotropic exchange interactions in the Co3II moiety of [Co3W(D2O)2(ZnW9O34)2](12-)--A magnetic and inelastic neutron scattering study.

Abstract

The ground-state properties of a Co3II moiety encapsulated in a polyoxometalate anion were investigated by combining measurements of specific heat, magnetic susceptibility, and low-temperature magnetization with a detailed inelastic neutron scattering (INS) study on a fully deuterated polycrystalline sample of Na12[Co3W(D2O)2(ZnW9O34)2].40D2O (Co3). The… (More)

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@article{ClementeJuan2002MagnetismIP, title={Magnetism in polyoxometalates: anisotropic exchange interactions in the Co3II moiety of [Co3W(D2O)2(ZnW9O34)2](12-)--A magnetic and inelastic neutron scattering study.}, author={Juan Modesto Clemente-Juan and Eugenio Coronado and Alejandro Gaita-Ari{\~n}o and Carlos Gim{\'e}nez-Saiz and Gr{\'e}gory Chaboussant and Hans-Ulrich G{\"{u}del and Ramon Burriel and Hannu Mutka}, journal={Chemistry}, year={2002}, volume={8 24}, pages={5701-8} }