Magnetic circular dichroism and density functional theory studies of electronic structure and bonding in cobalt(ii)-N-heterocyclic carbene complexes.

Abstract

The combination of simple cobalt salts and N-heterocyclic carbene (NHC) ligands has been highly effective in C-H functionalization, hydroarylation and cross-coupling catalysis, though displaying a strong dependence on the identity of the NHC ligand. In addition, reactions effective with NHC ligands are often ineffective with phosphine ligands, further… (More)
DOI: 10.1039/c7dt01748k

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