M5M – Key compounds of the research field metal–metal quintuple bonding

@article{Noor2015M5MK,
  title={M5M – Key compounds of the research field metal–metal quintuple bonding},
  author={A. Noor and R. Kempe},
  journal={Inorganica Chimica Acta},
  year={2015},
  volume={424},
  pages={75-82}
}
Abstract Since, the isolation of the first stable formally quintuple bonded chromium dimer Ar′CrCrAr′ (Ar′ = 2,6-(2,6-iPr2C6H3)2C6H3) in 2005 by Power and coworkers, the chemistry of high bond order molecules has experienced a renaissance and again has become an emerging field. A number of stable homobimetallic compounds of chromium and molybdenum, containing mostly sterically bulky N-ligands have been isolated and experimentally and theoretically studied within this renaissance. On one hand… Expand
Lithium Di- and trimethyl dimolybdenum(II) complexes with Mo-Mo quadruple bonds and bridging methyl groups.
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