Luminescent bis-tridentate ruthenium(II) and osmium(II) complexes based on terpyridyl-imidazole ligand: synthesis, structural characterization, photophysical, electrochemical, and solvent dependence studies.

@article{Bhaumik2012LuminescentBR,
  title={Luminescent bis-tridentate ruthenium(II) and osmium(II) complexes based on terpyridyl-imidazole ligand: synthesis, structural characterization, photophysical, electrochemical, and solvent dependence studies.},
  author={Chanchal Bhaumik and Shyamal Das and Dinesh Maity and Sujoy Baitalik},
  journal={Dalton transactions},
  year={2012},
  volume={41 8},
  pages={
          2427-38
        }
}
Homo- and heteroleptic bis-tridentate ruthenium(II) and osmium(II) complexes of compositions [(tpy-PhCH(3))Ru(tpy-HImzPh(3))](ClO(4))(2) (1), [(H(2)pbbzim)Ru(tpy-HImzPh(3))] (ClO(4))(2) (2) and [M(tpy-HImzPh(3))(2)](ClO(4))(2) [M = Ru(II) (3) and Os(II) (4)], where tpy-PhCH(3) = p-methylphenyl terpyridine, H(2)pbbzim = 2,6-bis(benzimidazole-2-yl)pyridine and tpy-HImzPh(3) = 4'-[4-(4,5-diphenyl-1H-imidazol-2-yl)-phenyl]-[2,2':6',2'']terpyridine, have been synthesized and characterized by using… Expand
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