Luminescent Silver ( I ) and Copper ( I ) Systems Containing Pyridyl Phosphine Bridges

@inproceedings{Crespo2009LuminescentS,
  title={Luminescent Silver ( I ) and Copper ( I ) Systems Containing Pyridyl Phosphine Bridges},
  author={Olga Crespo and M Concepci{\'o}n Gimeno and Antonio Laguna and Carmen Larraz},
  year={2009}
}
Luminescent silver(I) and copper(I) complexes containing pyridylphosphine ligands have been synthesized and structurally characterized by single crystal X-ray diffraction methods. The reaction of Ag(OTf) (OTf = trifluoromethanesulfonate) with 2-pyridyldiphenylphosphine in different molar ratios gives the species [Ag2(OTf)2(μ-PPh2py)2] (1), [Ag(PPh2py)2]OTf (2), [Ag(PPh2py)3]OTf (3), and [Ag2(PPh2py)3](OTf)2 (4) with several modes of coordination of the pyridylphosphine. The oxidation of the… CONTINUE READING