Luminescent, three-coordinate azadipyrromethene complexes of d(10) copper, silver, and gold.


Boron azadipyrromethenes are red-light-absorbing dyes with chromophoric capabilities deriving from a conjugated, chelating framework. Reported here are tricoordinate copper(I), silver(I), and gold(I) complexes of a tetraphenylazadipyrromethene ligand. The new complexes are characterized by optical absorption and emission spectroscopy, multinuclear NMR, mass… (More)


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