Long-Range Intramolecular Electronic Communication in a Trinuclear Ruthenium Tropolonate Complex.

Abstract

Dinuclear and trinuclear ruthenium complexes, [Ru(trop)2(C2trop)Ru(dppe)Cp] [2b; trop = tropolonato, C2trop = ethynyltropolonato, dppe = 1,2-bis(diphenylphosphino)ethane] and [Ru(trop){(C2trop)Ru(dppe)Cp}2] (3), were synthesized, and their electronic and electrochemical properties were investigated in comparison with our previously reported complex [Ru(acac… (More)
DOI: 10.1021/acs.inorgchem.6b02249

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