Living and highly syndiotactic polymerization of methyl methacrylate and other methacrylates by tert‐butyllithiumtrialkylaluminium in toluene

@article{Kitayama1989LivingAH,
  title={Living and highly syndiotactic polymerization of methyl methacrylate and other methacrylates by tert‐butyllithiumtrialkylaluminium in toluene},
  author={Tatsuki Kitayama and Tetsunori Shinozaki and T Sakamoto and Masanori Yamamoto and Koichi Hatada},
  journal={Macromolecular Chemistry and Physics},
  year={1989},
  volume={15},
  pages={167-185}
}
Highly syndiotactic poly(methyl methacrylate)s (PMMAs) with narrow molecular weight distribution (MWD) were prepared by polymerization of MMA in toluene at low temperatures, initiated with tert-butyllithium (t-C4H9Li) combined with trialkylaluminium compounds such as triethyl-, tributyl-, and trioctylaluminium (mole ratio Al/Li ≥ 3). Polymerization was initiated by the t-C4H9 anion and proceeded in a living manner. Several alkyl methacrylates were also polymerized with t-C4H9Li-(n-C4H9)3Al to… 
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Control of Main-Chain Stereostructure of Graft Polymers via Stereospecific Anionic Copolymerization of Syndiotactic Poly(methyl methacrylate) Macromonomer Having Methacryloyl Function with Methacrylate Monomers
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