Lattice model of diffusion-limited bimolecular chemical reactions in confined environments.

Abstract

We study the effect of confinement on diffusion-limited bimolecular reactions within a lattice model where a small number of reactants diffuse among a much larger number of inert particles. When the number of inert particles is held constant, the rate of the reaction is slow for small reaction volumes due to limited mobility from crowding and for large… (More)

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