Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexes.

@article{Mader2007LargeGE,
  title={Large ground-state entropy changes for hydrogen atom transfer reactions of iron complexes.},
  author={Elizabeth A. Mader and Ernest R. Davidson and James M. Mayer},
  journal={Journal of the American Chemical Society},
  year={2007},
  volume={129 16},
  pages={
          5153-66
        }
}
Reported herein are the hydrogen atom transfer (HAT) reactions of two closely related dicationic iron tris(alpha-diimine) complexes. FeII(H2bip) (iron(II) tris[2,2'-bi-1,4,5,6-tetrahydropyrimidine]diperchlorate) and FeII(H2bim) (iron(II) tris[2,2'-bi-2-imidazoline]diperchlorate) both transfer H* to TEMPO (2,2,6,6-tetramethyl-1-piperidinoxyl) to yield the hydroxylamine, TEMPO-H, and the respective deprotonated iron(III) species, FeIII(Hbip) or FeIII(Hbim). The ground-state thermodynamic… Expand
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  • Adam Wu, J. Mayer
  • Chemistry, Medicine
  • Journal of the American Chemical Society
  • 2008
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