LaSr3F5(CN2)2: a prototype structure for mixed-valent Eu4F5(CN2)2.


The new compound LaSr(3)F(5)(CN(2))(2) was prepared and structurally characterized as a prototype structure for the remarkably distorted mixed-valent compound Eu(4)F(5)(CN(2))(2), which contains four distinct europium ions in the structure: one Eu(3+) and three Eu(2+). Instead of repeating the given distorted structural pattern, LaSr(3)F(5)(CN(2))(2) forms… (More)
DOI: 10.1021/ic302039q

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