Kinetics of Surface-Induced Dissociation of N(CH 3 ) 4 + and N(CD 3 ) 4 + Using Silicon Nanoparticle Assisted Laser

@inproceedings{Yoon2011KineticsOS,
  title={Kinetics of Surface-Induced Dissociation of N(CH 3 )  4  +   and N(CD 3 )  4  +   Using Silicon Nanoparticle Assisted Laser},
  author={Sung Hwan Yoon and Chaminda M. Gamage and Kent J Gillig and Vicki H. Wysocki},
  year={2011}
}
The implementation of surface-induced dissociation (SID) to study the fast dissociation kinetics (sub-microsecond dissociation) of peptides in a MALDI TOF instrument has been reported previously. Silicon nanoparticle assisted laser desorption/ionization (SPALDI) now allows the study of small molecule dissociation kinetics for ions formed with low initial source internal energy and without MALDI matrix interference. The dissociation kinetics of N(CH3)4 and N(CD3)4 were chosen for investigation… CONTINUE READING

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