Kinetics and mechanisms for the reactions of phenyl radical with ketene and its deuterated isotopomer: an experimental and theoretical study.

@article{Choi2004KineticsAM,
  title={Kinetics and mechanisms for the reactions of phenyl radical with ketene and its deuterated isotopomer: an experimental and theoretical study.},
  author={Y M Choi and M. C. Lin},
  journal={Chemphyschem : a European journal of chemical physics and physical chemistry},
  year={2004},
  volume={5 2},
  pages={225-32}
}
  • Y M Choi, M. C. Lin
  • Published 2004 in
    Chemphyschem : a European journal of chemical…
Kinetics and mechanism for the reaction of phenyl radical (C6H5) with ketene (H2C beta=C alpha=O) were studied by the cavity ring-down spectrometric (CRDS) technique and hybrid DFT and ab initio molecular orbital calculations. The C6H5 transition at 504.8 nm was used to detect the consumption of the phenyl radical in the reaction. The absolute overall rate… CONTINUE READING