Kinetics and mechanism of ruthenium tetroxide catalysed oxidation of cyclic alcohols by bromate in a base

@article{Singh1991KineticsAM,
  title={Kinetics and mechanism of ruthenium tetroxide catalysed oxidation of cyclic alcohols by bromate in a base},
  author={Bharat Singh and Sheila Srivastava},
  journal={Transition Metal Chemistry},
  year={1991},
  volume={16},
  pages={466-468}
}
SummaryKinetic investigations on the RuO4-catalysed oxidation of cyclopentanol (Cypol) and cyclohexanol (Cyhol) in alkaline KBrO3 in the presence of Hg(OAc)2 which acts as a bromide ion scavenger have been made in the 30°–45°C range. The reaction exhibits zero order kinetics in OH− and is first order with respect to BrO3−, substrate and RuO4. The influence of Hg(OAc)2 and ionic strength is insignificant. A transient complex, formed between HRuO5− (the active species of RuO4) and the cyclic… 
Mechanistic Study of Ruthenium(III) Catalyzed Oxidation of Cyclohexanone by Acidic Bromate
In this work, kinetics and mechanism of Ru(III) catalyzed oxidation of cyclohexanone by acidified solution of potassium bromate has been studied. Present study employ mercuric acetate Hg (OAc)2 as a
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TLDR
The kinetics of iridium(III)-catalysed oxidation of 1,2-ethanediol and 1,4-butanediol by N-bromoacetamide (NBA) in HClO4 in the presence of [Hg(OAc)2] as a scavenger for Br− have been investigated and (H2OBr)+ is postulated as the oxidizing species.
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Kinetics and mechanism of the Os(VIII) catalysed oxidation of crotonic acid (CA) by KBrO3 in alkaline medium have been investigated. Zero order dependence in [KBrO3] was observed, while first order
Studies on transition metal nitrido and oxo complexes. Part 161. The nature of the oxoruthenates involved in some rutheniumcatalysed organic oxidations
SummaryElectronic spectroscopy has been used to ascertain the nature of the oxoruthenates present in a number of organic oxidations catalysed by ruthenium complexes reported in the literature. The
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Kinetic  investigations  on  Pd(II)  catalyzed oxidation  of  dl-serine and  dl-threonine  by  acidic  solution of  potassium  bromate  in  the presence  of  mercuric  acetate,  as  a  scavenger 
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The kinetics of Ru(III) chloride-catalyzed oxidation of β-Alanine (NH3+CH2CH2COOH, β-Ala) by N–bromophthalimide (NBP) in aqueous perchloric acid medium was studied at 35 °C. The rate law followed a
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