Kinetics and colloidal parameters of miniemulsion polymerization of butyl acrylate

Abstract

BACKGROUND: The miniemulsion polymerization of butyl acrylate initiated by a macromonomeric azoinitiator (macroinimer, MIM) and stabilized by the non-ionic emulsifier Tween 60 (TW-60) was investigated. RESULTS: The monomer conversion and the polymerization rate increase with the amount of MIM and then decrease. The desorption rate constants were estimated… (More)

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