Kinetic properties for the complete series reactions of chlorophenols with OH radicals-relevance for dioxin formation.

@article{Xu2010KineticPF,
  title={Kinetic properties for the complete series reactions of chlorophenols with OH radicals-relevance for dioxin formation.},
  author={Fei Xu and Hui Wang and Qingzhu Zhang and Ruixue Zhang and Xiaohui Qu and Wenxing Wang},
  journal={Environmental science & technology},
  year={2010},
  volume={44 4},
  pages={
          1399-404
        }
}
The chlorophenoxy radical (CPR) is a key intermediate species in the formation of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs). In municipal waste incinerators, the reactions of chlorophenols with OH radicals play the most central role in the formation of chlorophenoxy radicals. In this paper, molecular orbital theory calculations have been performed to investigate the formation of chlorophenoxy radicals from the complete series reactions of 19 chlorophenol congeners with… CONTINUE READING

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