Kinetic and thermodynamic aspects of the regioselective addition of bifunctional hydroxylaminooxime-type HO-nucleophiles to Pt-complexed nitriles.

Abstract

The coupling between coordinated propiononitriles in trans-[PtCln(EtCN)2] (n = 2, 4) and the 1,2-hydroxylaminooximes HON(H)CMe2C(R)=NOH (R = Ph 1, Me 2) proceeds smoothly in CHCl(3) at ca. 40-45 degrees C and gives trans-[PtCln{NH=C(Et)ON(H)CMe2C(R)=NOH}2] (n = 2, R = Ph 5, Me 6; n = 4, R = Ph 7, Me 8) in 80-85% isolated yields. The reaction is highly… (More)

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Cite this paper

@article{Luzyanin2006KineticAT, title={Kinetic and thermodynamic aspects of the regioselective addition of bifunctional hydroxylaminooxime-type HO-nucleophiles to Pt-complexed nitriles.}, author={Konstantin V Luzyanin and Vadim Yu Kukushkin and Dr Maxim L Kuznetsov and Alexander D Ryabov and Markus Galanski and Matti Haukka and Eugene V Tretyakov and Victor I Ovcharenko and Maximilian N Kopylovich and Armando J L Pombeiro}, journal={Inorganic chemistry}, year={2006}, volume={45 5}, pages={2296-306} }