Kalorimetrische Messungen der Kristallisations-und Schmelzvorgänge an Polymeren

@article{Mller2007KalorimetrischeMD,
  title={Kalorimetrische Messungen der Kristallisations-und Schmelzvorg{\"a}nge an Polymeren},
  author={F. Horst M{\"u}ller and Horst Martin},
  journal={Journal of Polymer Science Part C: Polymer Symposia},
  year={2007},
  volume={6},
  pages={83-91}
}
  • F. H. Müller, H. Martin
  • Published 7 March 2007
  • Materials Science
  • Journal of Polymer Science Part C: Polymer Symposia
Crystallizing and melting of polymers as a function of sample history is investigated by means of a differential thermal analytic method developed for quantitative evaluation. Crystallization and the subsequent melting of the same polymer occur at temperatures differing by 12 to 18°C. The melt temperature and the time of keeping the sample in the molten state, the cooling rate and the course of cooling have a reproducible effect on the subsequent melting. The crystallization is followed at… 
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Rheological and thermal degradation properties of hyperbranched polyisoprene prepared by anionic polymerization
TLDR
The hyperbranched polyisoprene decomposed via multistep mechanism as manifested by the nonlinear relationship between α and Ea while the linear polymer exhibited a decline in Ea at higher conversions.

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