KINETICS OF THE GROUND STATE TRANSFORMATION IN Fe ( I 1 ) ( N , N-DICYCLOHEXYLTHIOUREA ) 6 ( C 104 ) 2

Abstract

The high spin complex Fe(I1) (N, N'-dicyclohexylthiourea)~(C10~)~ exists in two forms which only differ in the distortion from octahedral symmetry of the environment of the Fe ion. Thermodynamic data for the transformation from one form to the other as obtained from Mossbauer spectroscopy are presented and a method to derive kinetic parameters is described. 

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