## Diffusion in quasi-one-dimensional channels: A small system n, p, T, transition state theory for hopping times.

- Sheida Ahmadi, Richard K Bowles
- The Journal of chemical physics
- 2017

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@article{Corti2001IsothermalisobaricEF, title={Isothermal-isobaric ensemble for small systems.}, author={David S. Corti}, journal={Physical review. E, Statistical, nonlinear, and soft matter physics}, year={2001}, volume={64 1 Pt 2}, pages={ 016128 } }

- Published in Physical review. E, Statistical, nonlinear, and…2001
DOI:10.1103/PhysRevE.64.016128

The application of the isothermal-isobaric (N-P-T) ensemble to small systems is considered. In the small system limit, which is currently gaining in scientific and technological significance, a volume scale must be introduced in order to obtain a partition function that is dimensionless. The volume scale, however, must be carefully chosen since it depends upon the nature of the boundary separating the system from the surroundings. If the incorrect volume scale is used, the resulting N-P-T… CONTINUE READING