Corpus ID: 37876286

Isophthalato-based 2D coordination polymers of Eu(III), Gd(III), and Tb(III): enhancement of the terbium-centered luminescence through thiophene derivatization.

@article{BettencourtDias2005Isophthalatobased2C,
  title={Isophthalato-based 2D coordination polymers of Eu(III), Gd(III), and Tb(III): enhancement of the terbium-centered luminescence through thiophene derivatization.},
  author={Ana de Bettencourt-Dias},
  journal={Inorganic chemistry},
  year={2005},
  volume={44 8},
  pages={
          2734-41
        }
}
  • Ana de Bettencourt-Dias
  • Published in Inorganic chemistry 2005
  • Medicine
  • We present here the first examples of lanthanide ion complexes with only isophthalic acid or thiophenylisophthalic acid ligands. The complexes of isophthalic acid with Eu(3+) (1) and Tb(3+) (2) and the moderately soluble complexes of 5-thiophen-3-ylisophthalate with Eu(3+) (3), Gd(3+) (4), and Tb(3+) (5) were isolated as single crystals through gel crystallization. X-ray diffraction studies confirm the cross-linking structure of these complexes, which, in case of the thiophenyl derivatives… CONTINUE READING

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