Isomers of the trans-dichlorobis(2-methyl-1,2-diaminopropane) cobalt(III) cation

@inproceedings{Harnett1985IsomersOT,
  title={Isomers of the trans-dichlorobis(2-methyl-1,2-diaminopropane) cobalt(III) cation},
  author={Michelle Harnett and Donald A. House and Ward Thomas Robinson},
  year={1985}
}
Two isomers of trans -CoCl 2 (ibn) 2 + have been isolated from the reaction of dioxygen with methanolic solutions of CoCl 2 ·6H 2 O and the diamine. The most abundant is assigned the trans-gem -dimethyl configuration and the least abundant has been single crystal X-ray analysis of the ZnCl 4 2− (monohydrate) salt. Cis-gem -dimethyl- trans [CoCl 2 -(ibn) 2 ] 2 ZnCl 4 ·H 2 O crystallizes in the monoclinic space group P 2 1/ c , with a = 15.02(1), b = 11.100(2), c = 21.68(2), β = 105.64(7) and… CONTINUE READING