Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization

@article{Sharma2016IsocyanideON,
  title={Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization},
  author={Savita K. Sharma and Hyun Yun Kim and Patrick J. Rogler and Maxime A. Siegler and Kenneth D Karlin},
  journal={JBIC Journal of Biological Inorganic Chemistry},
  year={2016},
  volume={21},
  pages={729-743}
}
A series of ferrous-heme 2,6-dimethylphenyl isocyanide (DIMPI) and ferrous-heme mononitrosyl complexes have been synthesized and characterized. The heme portion of the complexes studied is varied with respect to the nature of the axial ligand, including complexes, where it is covalently tethered to the porphyrinate periphery. Reduced heme complexes, [(F8… CONTINUE READING