Iron-induced regio- and stereoselective addition of sulfenyl chlorides to alkynes by a radical pathway.


The radical addition of the Cl-S σ-bond in sulfenyl chlorides to various C-C triple bonds has been achieved with excellent regio- and stereoselectivity in the presence of a catalytic amount of a common iron salt. The reaction is compatible with a variety of functional groups and can be scaled up to the gram-scale with no loss in yield. As well as terminal… (More)
DOI: 10.1002/anie.201408121


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