Iron-Catalyzed Stereoselective Cross-Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents.

Abstract

A practical and highly stereoselective iron-catalyzed cross-coupling reaction of stereodefined enol carbamates and Grignard reagents to yield tri- and tetrasubstituted acrylates is reported. A facile method for the stereoselective generation of these enol carbamates has also been developed.

DOI: 10.1002/anie.201601899

Cite this paper

@article{Rivera2016IronCatalyzedSC, title={Iron-Catalyzed Stereoselective Cross-Coupling Reactions of Stereodefined Enol Carbamates with Grignard Reagents.}, author={Ana Cristina Parra Rivera and Raymond Still and Jonathan R Nitschke}, journal={Angewandte Chemie}, year={2016}, volume={55 23}, pages={6689-93} }