Iron(III) chloride and its coordination chemistry

@article{Cotton2018IronIIICA,
  title={Iron(III) chloride and its coordination chemistry},
  author={S. Cotton},
  journal={Journal of Coordination Chemistry},
  year={2018},
  volume={71},
  pages={3415 - 3443}
}
  • S. Cotton
  • Published 2018
  • Chemistry
  • Journal of Coordination Chemistry
  • Abstract The coordination chemistry of FeCl3 is distinctly different to that of the other 3d metal halides. It has a distinct preference for O-donor ligands. Although it primarily forms six-coordinate complexes, it has some distinctive features that set it apart from metals like Mn(II), Co(II), and Ni(II), such as the self-ionized complexes [FeL4Cl2]+ [FeCl4]−. There are a number of examples where very small changes in the coordination sphere tilt the balance between isomeric structures… CONTINUE READING

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