Iron(III) chloride and its coordination chemistry

@article{Cotton2018IronIIICA,
  title={Iron(III) chloride and its coordination chemistry},
  author={Simon A. Cotton},
  journal={Journal of Coordination Chemistry},
  year={2018},
  volume={71},
  pages={3415 - 3443}
}
  • S. Cotton
  • Published 2 November 2018
  • Chemistry
  • Journal of Coordination Chemistry
Abstract The coordination chemistry of FeCl3 is distinctly different to that of the other 3d metal halides. It has a distinct preference for O-donor ligands. Although it primarily forms six-coordinate complexes, it has some distinctive features that set it apart from metals like Mn(II), Co(II), and Ni(II), such as the self-ionized complexes [FeL4Cl2]+ [FeCl4]−. There are a number of examples where very small changes in the coordination sphere tilt the balance between isomeric structures… 
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References

SHOWING 1-10 OF 205 REFERENCES
Influence of the anion of FeIII salts on the product distribution in the oxidative degradation of a tetrapyridyl ligand
We have focused our interest on the tetrapyridyl ligand bis[di(2-pyridyl)methyl]amine (BDPMA) in order to prepare mononuclear non-heme iron(III) complexes as catalyst precursors in oxidation
Molecular structure of [trans-FeCl2(imidazole)4]Cl·THF·H2O
The structure of [trans-FeCl2(imidazole)4]Cl has been determined as the THF/H2O solvate. The Fe-Cl and Fe-N distances in the cation are shorter than analogous trans-FeCl2(L)4 compounds, concomitant
Tetrachloroferrate(III) Complexes Containing Some Heteroaromatic Organic Cations: Structures and Magnetic Properties
The crystal structures of tetrachloroferrate(III) complexes having stoichiometry (BH)+ [FeCl4]− (where B = isoquinoline and 4-aminopyridine) were determined at 100 K. While weak interactions,
Spectroscopic studies on pyridine N-oxide complexes of iron(III)
The complexes Fe(pyO)6(ClO4)3, Fe(pyO)6(NO3)3,2H2O, Fe(pyO)4(NO3)3,H2O, [Fe(pyO)4Cl2]+ClO4–,H2O, Fe(pyO)3X3(X = Cl or NCS) and Fe(pyO)2X3(X = Cl or Br) have been prepared. The stereochemistries of
Tetra­butyl­ammonium bromo­trichloro­ferrate(III)
The Fe3+ centre in the complex anion of the title compound, [(C4H9)4N][FeBrCl3], is surrounded by three chloride anions and one bromide anion. The Br atom in [FeBrCl3]− is disordered, replacing Cl
Iron(III) complexes of triphenylphosphine and triphenylarsine oxides; their electron paramagnetic resonance and vibrational spectra
E.p.r. spectra are reported for the complexes FeL4(ClO4)3 and FeL2X3(L = Ph3PO, X = Cl, Br, NO3,NCS; L = Ph3AsO, X = Cl, Br, NO3). The spin-Hamiltonian parameters D and λ deduced from these
Spectroscopic studies of some aquo-complexes of iron(III) and indium(III)
Raman spectra are reported for the complexes Fe(ClO4)3, 10H2O, Fe(NO3)3,9H2O,[Fe(OH2)4Cl2]+X–,nH2O (X = Cl–, n= 2; or X = SbCl6–, n= 4), and (NH4)2[MX5(OH2)](M = Fe, X = Cl; or M = In, X = Cl or Br),
Tetrabutyl­ammonium tetrachloro­ferrate(III)
In the title compound, [(C4H9)4N][FeCl4], the central FeIII atom in the anion is tetrahedrally coordinated by four Cl atoms, while the cation exists as a central N atom bonded to four n-butyl groups,
Ferric complexes of nitrogen-containing heterocyclic ligands; their electron paramagnetic resonance and vibrational spectra
The complexes Fe(pyrazole)3Cl3, Fe(3-methylpyrazole)3Cl3, Fe(py)4Cl3, Fe(pyrimidine)2Cl3, and Fe(pyrazine)5/2Cl3 have been prepared; the vibrational spectra of these and a number of similar, indium
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